Its very simle and easy one Follow me.... If you have several google talk accounts, you may want to run multiple instances of google talk at once. Here’s how to do it. Many users, including myself, like to have several different personalities on IM–Work, play, etc. By default google talk with only allow you to run instance of the program at a time. Here’s how to get around that Run google talk with the following switch: /nomutex If you installed google talk to the default location, you can easily create a shortcut to this setting. 1. Right-click on the desktop 2. Select New 3. Select Shortcut 4.Paste this into the text boxif you have 32 bit windows "c:\program files\google\google talk\googletalk.exe" /nomutex else it will show an error path not found . then you will have to find the path to the googletalk.exe in C: drive then paste the complete path and then To find the path just click on start button ...